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- W2009479627 abstract "We have characterized superstructures of thiacyanine J aggregates in aqueous electrolyte solution in the dye concentration range between 2.5 and 80 mM. Fluorescence microscopy, polarized-light microscopy, and atomic force microscopy proved that the individual thiacyanine J aggregate possessed a mesoscopic rectangular sheetlike morphology (∼3−7 μm wide and ∼10−30 μm long) consisting of a two-dimensional monomolecular layer of molecules. Synchrotron small-angle X-ray scattering revealed the superstructure of oriented monomolecular sheets which shows a disordered (nematic-like) or an ordered (smectic) layer alignment in solution. These superstructural behaviors can be interpreted in terms of the packing or alignments of the mesoscopic monomolecular sheets of the J aggregate as a function of the dye concentration." @default.
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- W2009479627 date "2003-09-16" @default.
- W2009479627 modified "2023-09-25" @default.
- W2009479627 title "Superstructures of Mesoscopic Monomolecular Sheets of Thiacyanine J Aggregates in Solution" @default.
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- W2009479627 doi "https://doi.org/10.1021/la035013f" @default.
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