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- W2009487780 abstract "Abstract N1,N2-disubstituted polyform-, -acet- and -benzamidines containing the 4,4′-substituted diphenyl methane unit were studied by means of 1H, 13C and 15N nuclear magnetic resonance (n.m.r.) in solution. The n.m.r. signals were assigned. For the polyacet- and -benzamidine slow tautomerism on the n.m.r. time scale resulted in separate signals for the amino and imino moiety due to preference for the E-anti configuration of the amidine group. This tautomerism was much faster for the polyformamidine due to cyclic dimerization of formamidine groups in the preferred E-syn configuration. In this case, the signals of the amino and imino moiety coalesced." @default.
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- W2009487780 date "1997-05-01" @default.
- W2009487780 modified "2023-09-25" @default.
- W2009487780 title "1H, 13C and 15N nuclear magnetic resonance studies of polyamidines prepared from di(4,4′-aminophenyl) methane and different triethyl orthoesters—polymers with a prototropic tautomerism" @default.
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- W2009487780 doi "https://doi.org/10.1016/s0032-3861(97)85591-7" @default.
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