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- W2009494089 abstract "The structure of ferric phosphate at room temperature was refined on a Dauphiné-twinned crystal using full-matrix least-squares methods. The final R value was 0.078 for 487 symmetry-independent reflections whose intensities were corrected for twinning. The structure was found to be isotypic with AlPO 4 (berlinite) with the space group P3 1 21 and four formula units in a unit cell defined by a = 5.036(2) and c = 11.255(4) Å. The structure is also closely related to that of α-quartz with a nearly doubled c-axis because of the ordering of Fe and P atoms. The PO 4 tetrahedron is almost regular with a mean P—O distance of 1.526 Å. The Fe 3+ ion is tetrahedrally coordinated with an average Fe—O distance of 1.853 Å." @default.
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- W2009494089 date "1975-07-15" @default.
- W2009494089 modified "2023-10-18" @default.
- W2009494089 title "Refinement of the Crystal Structure of the Low-quartz Modification of Ferric Phosphate" @default.
- W2009494089 doi "https://doi.org/10.1139/v75-287" @default.
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