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• W2009495576 abstract "Abstract The reference interaction site model (RISM) theory combined with the generalized Langevin/mode-coupling theory (MCT) is applied to the investigation of solvation dynamics in water. The dynamic response function SS(t) which measures the energy relaxation of the system is calculated with different model solutes. The RISM–MCT framework recently presented by Yamaguchi and coworkers [J. Chem. Phys., 117 (2002) 2216; Mol. Phys., 101 (2003) 1211] is shown to be applicable well to the realistic description of solvation dynamics. SS(t) initially relaxes with a Gaussian decay followed by an overdamping oscillation with the time period of 30 fs. As the multiplicity of the solute pole is increased, the magnitude of the SS(t) damping becomes smaller and relaxation gets slower." @default.
• W2009495576 created "2016-06-24" @default.
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• W2009495576 date "2005-05-01" @default.
• W2009495576 modified "2023-09-24" @default.
• W2009495576 title "Solvation dynamics in water investigated by RISM/mode-coupling theory" @default.
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• W2009495576 doi "https://doi.org/10.1016/j.molliq.2004.10.009" @default.
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