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• W2009502832 abstract "The palladium-catalyzed allylic alkylation reaction of 1,1-dimethylallyl acetate with dimethyl malonate is studied by a combination of isotope effects and theoretical calculations. A large 13C isotope effect of ≈1.037 is observed at the tertiary carbon, while small isotope effects are observed at the olefinic carbons. These results support rate-limiting ionization of a η2-Pd complex. The observed isotope effects are compared with predictions from calculational models employing either solvent models or ionization of an amidinium ion. The calculated transition structures are notably η2 in character, and the implications of this observation are discussed." @default.
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• W2009502832 date "2005-03-01" @default.
• W2009502832 modified "2023-09-27" @default.
• W2009502832 title "Isotope effects and the mechanism of palladium-catalyzed allylic alkylation" @default.
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• W2009502832 doi "https://doi.org/10.1016/j.tetlet.2005.01.088" @default.
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