FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2009508625> ?p ?o ?g. }

• W2009508625 endingPage "146" @default.
• W2009508625 startingPage "141" @default.
• W2009508625 abstract "Pentafluorosulfanylamines, R2NSF5 (R2NEt2N, piperidyl) react with AsF5 to give stable persulfuranonium hexafluoroarsenates, Et2NSF4+AsF6− (4) and PipSF4+AsF6− (5), respectively. At low temperatures, SF5NS(O)F2 forms an unstable adduct SF5NS(O)F2·AsF5 (12), which dissociates reversibly into the starting materials on warming, while the corresponding SF5NSF2·AsF5 (14) is readily decomposed in liquid SO2 to give OSF2 and AsF5·NSF3 (15). In the absence of solvent and in the presence of excess AsF5, slow decomposition to SF3+AsF6− and 15 was observed. [(Me2N)2SF2]2+ (AsF6−)2 (16) adds HF with the formation of a salt containing a pentacoordinated sulfur(VI) dication, [Me2NSF3NMe2H)2+ (AsF6-)2 (17). Pentafluorosulfanylamine, R2NSF5 (R2NEt2N, Piperidyl) reagieren mit AsF5 zu stabilen Persulfuranonium- Hexafluorarsenaten, Et2NSF4+ AsF6- (4) und PipSF4+ AsF6- (5). Bei tiefen Temperaturen, bildet SF5NS(O)F2 ein instabiles Addukt SF5NS(O)F2·AsF5 (12), das beim Erwärmen reversibel in die Ausgangsverbindungen dissoziiert. Das korrespondierende F5SNSF2·AsF5 (14) wird in flüssigem SO2 rasch zu OSF2 unde AsF5·NSF3 (15) zersetzt. Ohne Lösungsmittel erfolgt in Gegenwart von überschüssigem AsF5 langsam Zersetzung zu SF3+ AsF6− und 15 [(Me2N)2SF2]2+ (AsF6−)2 (16) addiert HF unter Bildung eines Salzes mit einem pentakoordiniertem Schwefel (VI)- Dikation [Me2NSF3NMe2H]2+(AsF6−)2 (17)." @default.
• W2009508625 created "2016-06-24" @default.
• W2009508625 creator A5016877578 @default.
• W2009508625 creator A5083819729 @default.
• W2009508625 date "1994-02-01" @default.
• W2009508625 modified "2023-10-12" @default.
• W2009508625 title "Pentakoordinierte Schwefel(VI)-Salze" @default.
• W2009508625 cites W1989937982 @default.
• W2009508625 cites W1992186044 @default.
• W2009508625 cites W1994278943 @default.
• W2009508625 cites W1999634889 @default.
• W2009508625 cites W2011372017 @default.
• W2009508625 cites W2024962539 @default.
• W2009508625 cites W2035075880 @default.
• W2009508625 cites W2037361804 @default.
• W2009508625 cites W2044236439 @default.
• W2009508625 cites W2053487871 @default.
• W2009508625 cites W2055679136 @default.
• W2009508625 cites W2075268636 @default.
• W2009508625 cites W2077646882 @default.
• W2009508625 cites W2081778569 @default.
• W2009508625 cites W2089836448 @default.
• W2009508625 cites W2091432224 @default.
• W2009508625 cites W2099495935 @default.
• W2009508625 cites W2110937651 @default.
• W2009508625 cites W2127639243 @default.
• W2009508625 cites W2139467587 @default.
• W2009508625 cites W2144340995 @default.
• W2009508625 cites W2950893543 @default.
• W2009508625 cites W2952481052 @default.
• W2009508625 cites W4229958929 @default.
• W2009508625 doi "https://doi.org/10.1016/0022-1139(93)03010-j" @default.
• W2009508625 hasPublicationYear "1994" @default.
• W2009508625 type Work @default.
• W2009508625 sameAs 2009508625 @default.
• W2009508625 citedByCount "3" @default.
• W2009508625 countsByYear W20095086252020 @default.
• W2009508625 crossrefType "journal-article" @default.
• W2009508625 hasAuthorship W2009508625A5016877578 @default.
• W2009508625 hasAuthorship W2009508625A5083819729 @default.
• W2009508625 hasConcept C108204754 @default.
• W2009508625 hasConcept C124681953 @default.
• W2009508625 hasConcept C155647269 @default.
• W2009508625 hasConcept C178790620 @default.
• W2009508625 hasConcept C185592680 @default.
• W2009508625 hasConcept C2780471494 @default.
• W2009508625 hasConceptScore W2009508625C108204754 @default.
• W2009508625 hasConceptScore W2009508625C124681953 @default.
• W2009508625 hasConceptScore W2009508625C155647269 @default.
• W2009508625 hasConceptScore W2009508625C178790620 @default.
• W2009508625 hasConceptScore W2009508625C185592680 @default.
• W2009508625 hasConceptScore W2009508625C2780471494 @default.
• W2009508625 hasIssue "2" @default.
• W2009508625 hasLocation W20095086251 @default.
• W2009508625 hasOpenAccess W2009508625 @default.
• W2009508625 hasPrimaryLocation W20095086251 @default.
• W2009508625 hasRelatedWork W1531601525 @default.
• W2009508625 hasRelatedWork W2319480705 @default.
• W2009508625 hasRelatedWork W2384464875 @default.
• W2009508625 hasRelatedWork W2606230654 @default.
• W2009508625 hasRelatedWork W2607424097 @default.
• W2009508625 hasRelatedWork W2748952813 @default.
• W2009508625 hasRelatedWork W2899084033 @default.
• W2009508625 hasRelatedWork W2948807893 @default.
• W2009508625 hasRelatedWork W4387497383 @default.
• W2009508625 hasRelatedWork W2778153218 @default.
• W2009508625 hasVolume "66" @default.
• W2009508625 isParatext "false" @default.
• W2009508625 isRetracted "false" @default.
• W2009508625 magId "2009508625" @default.
• W2009508625 workType "article" @default.