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- W2009514630 abstract "Various substituents have been introduced into the inner or the outer position of the dithia[3.3.1]metacyclophanes (MCPs). Conformational properties of these MCPs are evaluated by variable temperature 1H-NMR spectral measurements, IR measurements, computer calculation and X-ray structural analyses. It has been found that the conformations of dithia[3.3.1]MCPs are affected by not only the steric effect of the inner or the outer substituent but also by the electronic nature of the component aromatic ring. Furthermore, a weak interaction such as NH–π interaction or hydrogen-bonding also regulates their conformation." @default.
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- W2009514630 date "2001-10-05" @default.
- W2009514630 modified "2023-10-16" @default.
- W2009514630 title "Preparation and structural properties of dithia[3.3.1]metacyclophanes" @default.
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- W2009514630 doi "https://doi.org/10.1039/b106154m" @default.
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