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- W2009544513 abstract "The rigid sphere model is applied to the explanation of the nature of the rotational phase transitions in the complex antifluorite and elpasolite compounds. In order to calculate the phase transition temperature Tc the extended formulas for the lattice pressure are introduced including both, Coulomb interaction of the effective ion charges and dispersive interactions. The dependence of Tc as a function of the lattice constant, dTc/da, are determined for seven families of the antifluorites and elpasolites from experimental data and calculated based on the rigid sphere model. Effects of the cavity shape, the complexity of NH cation, effective ionic charges, and dispersive interactions on dTc/da are discussed. [Russian Text Ignored]." @default.
- W2009544513 created "2016-06-24" @default.
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- W2009544513 date "1989-12-16" @default.
- W2009544513 modified "2023-10-18" @default.
- W2009544513 title "Rigid sphere model of the phase transitions in complex antifluorite and elpasolite compounds" @default.
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- W2009544513 doi "https://doi.org/10.1002/pssa.2211160224" @default.
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