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- W2009548861 abstract "Abstract LiMg2RuH7 and its deuteride were synthesized by sintering mixtures of LiH, magnesium and ruthenium powders at 500–550 °C and a hydrogen (deuterium) pressure of 120–155 bar, and characterized by X-ray and neutron powder diffraction. The yellow powder crystallizes with hexagonal symmetry ( space group , P6 3 /mmc; hydride - a = 4.7060(1) A , c = 10.6960(2) A ; deuteride - a = 4.6998(1) A , c = 10.6674(3) A ). The structure is an ordered substitution variant of Mg3ReH7. It contains a nearly regular octahedral 18-electron [Ru(II)D6]4− complex with bond distances [Ru-6D1] = 1.704(7) A , and a deuteride anion D− coordinated in a trigonal bipyramidal configuration by two close magnesium and three distant lithium cations with bond distances [D2-2Mg] = 1.852(6) A and [D2−3Li] = 2.7134(1) A respectively." @default.
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- W2009548861 date "1994-08-01" @default.
- W2009548861 modified "2023-09-27" @default.
- W2009548861 title "LiMg2RuH7, a new quaternary metal hydride containing octahedral [Ru(H)H6]4− complex anions" @default.
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- W2009548861 doi "https://doi.org/10.1016/0925-8388(94)90144-9" @default.
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