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- W2009559954 abstract "Discussions are made concerning realistic mechanisms for the origin of L-amino acids in the biosphere. As the most plausible mechanism, it is proposed that a mixture of racemic amino acids in the prebiotic sea caused spontaneous and effective optical resolution through self crystallization, even if asymmetric synthesis of a single amino acid has never occurred without the aid of an optically active molecule. This hypothesis is based on recrystallization of a mixture of D,L-amino acids in the presence of excess of D,L-asparagine (Asn). The enantiomeric excess (ee) of each amino acid in the resulting crystals indicates that crystallization of co-existing amino acids with the configuration same as that of Asn took place, although it was incidental whether the enrichment occurred in L- or D-amino acids. In addition, the resulting ee was sufficiently high (up to 100%) to account for the predominance of L-amino acids on the earth." @default.
- W2009559954 created "2016-06-24" @default.
- W2009559954 creator A5023077370 @default.
- W2009559954 date "2010-05-13" @default.
- W2009559954 modified "2023-09-23" @default.
- W2009559954 title "Origin of Homochirality of Amino Acids in the Biosphere" @default.
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- W2009559954 doi "https://doi.org/10.3390/sym2021022" @default.
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