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- W2009592020 abstract "Reaction of 6-chloro,9-(2-acetoxyethoxymethyl)purine 1 with ethyl cynoacetat, malononitrile and diethyl malonate in presence of NaH and DMF yielded the corresponding 6-methylidene derivatives 2a-c, which were deprotected by treatment with methanolic Ammonia to yield 3a-c. During the reaction of 1 with cyanoacetamide deacetylation took place spontaneously resulting in the deprotected acyclic nucleoside 4. Treatment of 2a with methyliodide in presence of NaH and DMF yielded the N-methyl derivative 5. NMR and mass spectra of the synthesized compounds are discussed." @default.
- W2009592020 created "2016-06-24" @default.
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- W2009592020 date "2010-08-18" @default.
- W2009592020 modified "2023-09-26" @default.
- W2009592020 title "ChemInform Abstract: Synthesis of Some 6-Methylidene-9-purine Acyclic Nucleosides with Expected anti-HIV Activity." @default.
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- W2009592020 doi "https://doi.org/10.1002/chin.199445236" @default.
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