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- W2009596004 abstract "Modifying benzoic acid with a cross-linking molecule (3-aminopropyl)triethoxysilane (abbreviated as APES), a fictional molecular bridge with double reactivity was achieved by the amidation reaction between them. Then the modified functional molecule, which behaving as a bridge, both coordinate with terbium ion through amide’s oxygen atom and form the Si–O chemical bond in an in situ sol–gel process with matrix precursor (tetraethoxysilane, TEOS). As a result, a novel molecular hybrid material (Tb-BA-APES) with double chemical bond (Tb–O coordination bond and Si–O covalent bond) was constructed. The strong luminescence of Tb3+ substantiates optimum energy couple and effective intramolecular energy transfer between the triplet state energy of modified ligand bridge and emissive energy level of Tb3+. Especially SEM of the molecular hybrid material exhibits unexpected microlotus root-like pore morphology." @default.
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- W2009596004 date "2006-07-01" @default.
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- W2009596004 title "Construction of hybrid material with double chemical bond from functional bridge ligand: Molecular modification, lotus root-like micromorphology and strong luminescence" @default.
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- W2009596004 doi "https://doi.org/10.1016/j.optmat.2005.08.008" @default.
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