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- W2009600584 abstract "Abstract The catalytic oxidation of naphthalenes was investigated. Hydrogen peroxide (30% aqueous) was used as an oxygen source, and 2,2’-dinitro-4,4’-ditrifluoromethyldiphenyl diselenide was the oxygen-transfer catalyst. Unsubstituted naphthols produce trans-2-carboxycinnamic acid in nearly quantitative yields. Both naphthols bearing substituents on the conjugated ring deliver corresponding trans-2-carboxycinnamic acids in good to excellent yields. The 1,7- and 2,6-hydronaphthoquinones, substituted by carboxy and carboxymethyl groups, produce hydroxycinnamic acids in satisfactory to excellent yields. A catalytic domino reaction mechanism is proposed." @default.
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- W2009600584 date "2012-09-01" @default.
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- W2009600584 title "OxofunctionalizedTrans-2-carboxycinnamic Acids by Catalytic Domino Oxidation of Naphthols and Hydronaphthoquinones" @default.
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- W2009600584 doi "https://doi.org/10.1080/00397911.2011.561945" @default.
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