FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2009635903> ?p ?o ?g. }

• W2009635903 endingPage "2190" @default.
• W2009635903 startingPage "2177" @default.
• W2009635903 abstract "Experiments directed toward elucidating the nature of fragments produced by the photodissociation of ClN3 have been performed. The utlraviolet absorption spectrum of this molecule exhibits three features between 300 and 170 nm, with λmax = 250, 205, and &lt;170 nm. The shortest wavelength feature (whose maximum was not resolved) was the strongest of the three, with ε170 = 5000 ℓ mol−1 cm−1. Photolysis of ClN3 at 193 nm produces N2 and NCl fragments in both the singlet and triplet manifolds. In the singlet manifold of fragments, emission from electronically excited NCl(b 1Σ+) was observed. The NCl(b 1Σ+) molecules are also vibrationally excited, and emission from levels as high as v′ = 10 was recorded. Time resolution of the NCl(b 1Σ+) emission indicated that the higher vibrational levels were quenched by the gas mixture (∼3% ClN3 in helium) much more rapidly than the lower vibrational levels. The rate constant for quenching of the low v′ levels (v′ = 0–2) of NCl(b 1Σ+) was determined to be kQ = (1.72±0.05)×103 s−1 Torr−1; the rate constant for quenching of the higher levels (v′?8) was found to be kQ = (3.8±0.2)×104 s−1 Torr−1. The spontaneous emission rate for NCl(b 1Σ+), v′ = 0–2, was measured to be A = 1590±160 s−1. In the triplet manifold of fragments, photolysis at 193 nm produces excited N2(A 3Σ+u) metastable molecules. The presence of this species was determined from the observation of N2(C 3Πu)→(B 3Πg) emission produced by energy pooling processes, and from the excitation of NO by energy transfer from the N2 metastables. Photolysis of ClN3 produces at 193 nm excited singlet and triplet fragments with comparable probability. Photolysis at 249 nm also generates both excited singlet and triplet NCl and N2 fragments. Emission from vibrationally excited NCl(b 1Σ+) was again observed, and the initial vibrational distribution appeared to be similar to that found for photolysis at 193 nm. The yields for production of NCl(b 1Σ+) at 193 and 249 nm are approximately equal. Photolysis at 249 nm also produces N2(A 3Σ+u) fragments, although in substantially smaller yield than found at 193 nm." @default.
• W2009635903 created "2016-06-24" @default.
• W2009635903 creator A5010066007 @default.
• W2009635903 creator A5043956562 @default.
• W2009635903 creator A5077706769 @default.
• W2009635903 creator A5088823463 @default.
• W2009635903 date "1981-09-01" @default.
• W2009635903 modified "2023-10-16" @default.
• W2009635903 title "Photodissociation of ClN3 at 193 and 249 nm" @default.
• W2009635903 cites W1967536594 @default.
• W2009635903 cites W1968736683 @default.
• W2009635903 cites W1972410820 @default.
• W2009635903 cites W1974636991 @default.
• W2009635903 cites W1986920204 @default.
• W2009635903 cites W1987366410 @default.
• W2009635903 cites W1988742674 @default.
• W2009635903 cites W1991198246 @default.
• W2009635903 cites W1994588009 @default.
• W2009635903 cites W1997104578 @default.
• W2009635903 cites W2011264563 @default.
• W2009635903 cites W2019667359 @default.
• W2009635903 cites W2021143320 @default.
• W2009635903 cites W2033118817 @default.
• W2009635903 cites W2037478217 @default.
• W2009635903 cites W2038112462 @default.
• W2009635903 cites W2042213575 @default.
• W2009635903 cites W2055947483 @default.
• W2009635903 cites W2056784647 @default.
• W2009635903 cites W2073768038 @default.
• W2009635903 cites W2076018912 @default.
• W2009635903 cites W2081188848 @default.
• W2009635903 cites W2084146788 @default.
• W2009635903 cites W2090980943 @default.
• W2009635903 cites W2126152578 @default.
• W2009635903 cites W2158508663 @default.
• W2009635903 cites W2312764955 @default.
• W2009635903 cites W2312939815 @default.
• W2009635903 cites W2317552976 @default.
• W2009635903 cites W2978637713 @default.
• W2009635903 cites W3023896062 @default.
• W2009635903 doi "https://doi.org/10.1063/1.442330" @default.
• W2009635903 hasPublicationYear "1981" @default.
• W2009635903 type Work @default.
• W2009635903 sameAs 2009635903 @default.
• W2009635903 citedByCount "46" @default.
• W2009635903 countsByYear W20096359032013 @default.
• W2009635903 countsByYear W20096359032014 @default.
• W2009635903 crossrefType "journal-article" @default.
• W2009635903 hasAuthorship W2009635903A5010066007 @default.
• W2009635903 hasAuthorship W2009635903A5043956562 @default.
• W2009635903 hasAuthorship W2009635903A5077706769 @default.
• W2009635903 hasAuthorship W2009635903A5088823463 @default.
• W2009635903 hasConcept C113196181 @default.
• W2009635903 hasConcept C121332964 @default.
• W2009635903 hasConcept C121745418 @default.
• W2009635903 hasConcept C148898269 @default.
• W2009635903 hasConcept C178790620 @default.
• W2009635903 hasConcept C181500209 @default.
• W2009635903 hasConcept C184779094 @default.
• W2009635903 hasConcept C185592680 @default.
• W2009635903 hasConcept C30646810 @default.
• W2009635903 hasConcept C32909587 @default.
• W2009635903 hasConcept C33062035 @default.
• W2009635903 hasConcept C43617362 @default.
• W2009635903 hasConcept C54582936 @default.
• W2009635903 hasConcept C62520636 @default.
• W2009635903 hasConcept C75473681 @default.
• W2009635903 hasConcept C89464430 @default.
• W2009635903 hasConcept C91881484 @default.
• W2009635903 hasConcept C93391505 @default.
• W2009635903 hasConcept C97355855 @default.
• W2009635903 hasConceptScore W2009635903C113196181 @default.
• W2009635903 hasConceptScore W2009635903C121332964 @default.
• W2009635903 hasConceptScore W2009635903C121745418 @default.
• W2009635903 hasConceptScore W2009635903C148898269 @default.
• W2009635903 hasConceptScore W2009635903C178790620 @default.
• W2009635903 hasConceptScore W2009635903C181500209 @default.
• W2009635903 hasConceptScore W2009635903C184779094 @default.
• W2009635903 hasConceptScore W2009635903C185592680 @default.
• W2009635903 hasConceptScore W2009635903C30646810 @default.
• W2009635903 hasConceptScore W2009635903C32909587 @default.
• W2009635903 hasConceptScore W2009635903C33062035 @default.
• W2009635903 hasConceptScore W2009635903C43617362 @default.
• W2009635903 hasConceptScore W2009635903C54582936 @default.
• W2009635903 hasConceptScore W2009635903C62520636 @default.
• W2009635903 hasConceptScore W2009635903C75473681 @default.
• W2009635903 hasConceptScore W2009635903C89464430 @default.
• W2009635903 hasConceptScore W2009635903C91881484 @default.
• W2009635903 hasConceptScore W2009635903C93391505 @default.
• W2009635903 hasConceptScore W2009635903C97355855 @default.
• W2009635903 hasIssue "5" @default.
• W2009635903 hasLocation W20096359031 @default.
• W2009635903 hasOpenAccess W2009635903 @default.
• W2009635903 hasPrimaryLocation W20096359031 @default.
• W2009635903 hasRelatedWork W1976266756 @default.
• W2009635903 hasRelatedWork W1980229862 @default.
• W2009635903 hasRelatedWork W2001650568 @default.
• W2009635903 hasRelatedWork W2013989409 @default.

• next