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- W2009642638 abstract "The conformational analysis of a number of N-hexopyranosylimidazoles and their tetra-O-acetyl derivatives has been carried out using 1H-n.m.r. data obtained after computer simulation of spectra. Evidence is presented that, for some compounds, mixtures of 4C1 and 1C4 conformers are present in solution, and the possible contributions of steric effects and polar, reverse anomeric effects are discussed. It is concluded that the results can in large part be accounted for by steric factors, but that the operation of additional polar factors is likely. Present rationalisations of the reverse anomeric effect are discussed and a stereoelectronic interpretation is presented. The conformations of the exocyclic hydroxymethyl groups are analysed and shown to give additional information about the presence of alternative chair conformations." @default.
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- W2009642638 title "The enzyme-inhibitory properties of 1-α- and 1-β-D-glucopyranosyl-imidazoles" @default.
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- W2009642638 doi "https://doi.org/10.1016/s0008-6215(00)83036-0" @default.
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