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- W2009668833 abstract "Abstract We report here on the observation of the Zr⋯F–CH 3 van der Waals complexes in a laser ablation – supersonic expansion source. The complexes are studied using a combination of laser spectroscopy and time-of-flight mass spectrometric detection. We show that the (1:1) Zr⋯F–CH 3 complex is stable in the ground electronic state. By a ground state photodepletion method, we have characterized one of the transitions in the 600–700 nm region as correlating asymptotically with the z 3 F 2 0 ← a 3 F 2 atomic transition from the ground state of free Zr atom. The corresponding excited state of the Zr⋯F–CH 3 complex is reactive with activation of the C–F bond." @default.
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- W2009668833 date "2010-05-01" @default.
- W2009668833 modified "2023-09-27" @default.
- W2009668833 title "Photodepletion measurements of the Zr⋯F–CH3 van der Waals complex" @default.
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- W2009668833 doi "https://doi.org/10.1016/j.cplett.2010.03.083" @default.
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