Matches in SemOpenAlex for { <https://semopenalex.org/work/W2009702543> ?p ?o ?g. }
- W2009702543 endingPage "227" @default.
- W2009702543 startingPage "217" @default.
- W2009702543 abstract "The crystal structure of deuterated topaz [topaz-OD; Al2SiO4(OD)2], synthesized at 10 GPa and 800 °C, has been determined using neutron powder diffraction at pressures up to 7.5 GPa. The linear axial compressibilities obtained from regressions of the lattice constants vs. pressure are βa = 1.87(1) × 10-3 GPa-1, βb = 1.71(1) × 10-3 GPa-1, and βc = 2.73(1) × 10-3 GPa-1. The occupancy of the D1 site was found to be greater than that of D2, as shown independently using neutron diffraction and infrared spectra at ambient conditions. A bifurcated hydrogen bond involving the D1 site, O4-D1···O2 and O4- D1···O3, and a trifurcated hydrogen bond involving D2 site, O4-D2···O1, O4-D2···O2, and O4-D2···O4 are proposed for hydrogen-bond donor and acceptor pairs in addition to those reported previously. The observed pressure dependences of the hydrogen-bonding geometry show that these donor and acceptor pairs are classifiable into two types of interaction: (1) those that strengthen as a function of pressure (O4-D1···O3, O4-D2···O2, and O4-D2···O4) and (2) those that weaken (O4-D1···O1 and O4-D2···O1). These results also demonstrate that the reason for the contrasting behavior of the ν(OH) between F-rich natural topaz and topaz-OH are both the cooperative effect, O4-D2···O4-D1···O3, and the increasing Al-O4 distance." @default.
- W2009702543 created "2016-06-24" @default.
- W2009702543 creator A5023871557 @default.
- W2009702543 creator A5024353876 @default.
- W2009702543 creator A5038444727 @default.
- W2009702543 creator A5058276406 @default.
- W2009702543 creator A5068476084 @default.
- W2009702543 creator A5070596628 @default.
- W2009702543 date "2008-01-01" @default.
- W2009702543 modified "2023-10-01" @default.
- W2009702543 title "Pressure dependence of the hydrogen-bond geometry in topaz-OD from neutron powder diffraction" @default.
- W2009702543 cites W142818576 @default.
- W2009702543 cites W1568794184 @default.
- W2009702543 cites W1963536831 @default.
- W2009702543 cites W1978850296 @default.
- W2009702543 cites W1978890814 @default.
- W2009702543 cites W1980762243 @default.
- W2009702543 cites W1987756479 @default.
- W2009702543 cites W1987759430 @default.
- W2009702543 cites W1988479039 @default.
- W2009702543 cites W1995741381 @default.
- W2009702543 cites W1998018696 @default.
- W2009702543 cites W2004776935 @default.
- W2009702543 cites W2006657063 @default.
- W2009702543 cites W2009910922 @default.
- W2009702543 cites W2027581929 @default.
- W2009702543 cites W2040349308 @default.
- W2009702543 cites W2046094749 @default.
- W2009702543 cites W2052678511 @default.
- W2009702543 cites W2053767862 @default.
- W2009702543 cites W2062028761 @default.
- W2009702543 cites W2064060984 @default.
- W2009702543 cites W2072572420 @default.
- W2009702543 cites W2085337372 @default.
- W2009702543 cites W2092912777 @default.
- W2009702543 cites W2110877783 @default.
- W2009702543 cites W2162845664 @default.
- W2009702543 cites W2234998704 @default.
- W2009702543 cites W2268825755 @default.
- W2009702543 cites W2290555239 @default.
- W2009702543 cites W2309794511 @default.
- W2009702543 cites W2316822864 @default.
- W2009702543 cites W2317323977 @default.
- W2009702543 cites W2430336767 @default.
- W2009702543 cites W2490154238 @default.
- W2009702543 cites W2521170567 @default.
- W2009702543 cites W2522025200 @default.
- W2009702543 cites W2566934992 @default.
- W2009702543 cites W2913247781 @default.
- W2009702543 cites W2914050657 @default.
- W2009702543 cites W625272620 @default.
- W2009702543 cites W2070932698 @default.
- W2009702543 cites W23647234 @default.
- W2009702543 doi "https://doi.org/10.2138/am.2008.2483" @default.
- W2009702543 hasPublicationYear "2008" @default.
- W2009702543 type Work @default.
- W2009702543 sameAs 2009702543 @default.
- W2009702543 citedByCount "12" @default.
- W2009702543 countsByYear W20097025432014 @default.
- W2009702543 countsByYear W20097025432016 @default.
- W2009702543 countsByYear W20097025432017 @default.
- W2009702543 countsByYear W20097025432020 @default.
- W2009702543 countsByYear W20097025432021 @default.
- W2009702543 countsByYear W20097025432022 @default.
- W2009702543 countsByYear W20097025432023 @default.
- W2009702543 crossrefType "journal-article" @default.
- W2009702543 hasAuthorship W2009702543A5023871557 @default.
- W2009702543 hasAuthorship W2009702543A5024353876 @default.
- W2009702543 hasAuthorship W2009702543A5038444727 @default.
- W2009702543 hasAuthorship W2009702543A5058276406 @default.
- W2009702543 hasAuthorship W2009702543A5068476084 @default.
- W2009702543 hasAuthorship W2009702543A5070596628 @default.
- W2009702543 hasConcept C112887158 @default.
- W2009702543 hasConcept C115624301 @default.
- W2009702543 hasConcept C120665830 @default.
- W2009702543 hasConcept C121332964 @default.
- W2009702543 hasConcept C152568617 @default.
- W2009702543 hasConcept C155860418 @default.
- W2009702543 hasConcept C178790620 @default.
- W2009702543 hasConcept C184779094 @default.
- W2009702543 hasConcept C185039092 @default.
- W2009702543 hasConcept C185544564 @default.
- W2009702543 hasConcept C185592680 @default.
- W2009702543 hasConcept C193547582 @default.
- W2009702543 hasConcept C199289684 @default.
- W2009702543 hasConcept C207114421 @default.
- W2009702543 hasConcept C26873012 @default.
- W2009702543 hasConcept C2777825866 @default.
- W2009702543 hasConcept C2779892579 @default.
- W2009702543 hasConcept C32909587 @default.
- W2009702543 hasConcept C512968161 @default.
- W2009702543 hasConcept C58364064 @default.
- W2009702543 hasConcept C73585123 @default.
- W2009702543 hasConcept C8010536 @default.
- W2009702543 hasConceptScore W2009702543C112887158 @default.
- W2009702543 hasConceptScore W2009702543C115624301 @default.
- W2009702543 hasConceptScore W2009702543C120665830 @default.
- W2009702543 hasConceptScore W2009702543C121332964 @default.