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- W2009713078 abstract "Both TiC and core-shelled [email protected]2 are investigated as catalyst supports for proton exchange membrane fuel cells (PEMFCs). TiC is thermally stable, possesses both low solubility in sulphuric acid and high electronic conductivity. However, TiC undergoes irreversible electrochemical oxidation in dilute perchloric acid and the operating potential range of 0–1.2 VRHE. [email protected]2 core–shell composite is found to be more stable than TiC. Both these materials are used as supports for Pt and Pt–Pd alloy catalysts (Pt/TiC, Pt3Pd/TiC and Pt3Pd/[email protected]2) and are synthesized by microwave-assisted polyol process. The catalytic activities of both Pt3Pd/TiC and Pt3Pd/[email protected]2 toward the oxygen reduction reaction (ORR) are much higher than those for Pt/TiC. Accelerated durability tests show that TiC supported catalysts are not electrochemically stable. The corresponding [email protected]2 supported catalyst is more stable than that supported by TiC, indicating that with a protective oxide layer on the TiC core, [email protected]2 is a promising PEMFC catalyst support." @default.
- W2009713078 created "2016-06-24" @default.
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- W2009713078 date "2012-05-01" @default.
- W2009713078 modified "2023-10-18" @default.
- W2009713078 title "Titanium carbide and its core-shelled derivative TiC@TiO2 as catalyst supports for proton exchange membrane fuel cells" @default.
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- W2009713078 doi "https://doi.org/10.1016/j.electacta.2012.03.039" @default.
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