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- W2009729941 abstract "A theoretical study of homologous series of triphenylene hexaesters and hexaethers, disc-like mesogenic molecules, has been undertaken with semi-empirical methods. Preferential conformations of an isolated molecule, a pair of molecules and a set of molecules have been established For butyl and further homologues, hexaesters give irregular columns, resulting in piled pairs, with distances d and d' equal to 3.75 and 4.45 A between neighbouring aromatic cores. On the other hand hexaethers give regular columns (d ≃ 3.28 A) of helicoidal type with a pitch equal to 14 A. These results are in agreement with data from X-ray diffraction on the mesophase." @default.
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- W2009729941 date "1982-01-01" @default.
- W2009729941 modified "2023-09-25" @default.
- W2009729941 title "Molecular arrangement of mesogenic disc-like compounds : the hexa-n-alkoxy and hexa-n-alkanoyloxy triphenylenes" @default.
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- W2009729941 doi "https://doi.org/10.1051/jphys:01982004302035500" @default.
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