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- W2009740282 abstract "The polarographic study of 21 N1-substituted sulfa drugs has shown that the overall reduction process on an Hg electrode depends on the protonicity of the solvent and on the number of substituents on the N1 nitrogen (mono- or disubstituted). However, these features do not appear to influence the E1/2 values as they maintain a strict correlation in aprotic (DMF) vs. protic medium (C2H5OH), regardless of the number of substituents on amidic nitrogen. It has also been shown that the N1-substituents cause large shifts of the half-wave potential, so ΔE1/2 can be used as a kind of “substituent constant”. Correlations with pKa and spectroscopic data, as well as with the antibacterial potency of these compounds, have been obtained and discussed." @default.
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- W2009740282 date "1980-03-01" @default.
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- W2009740282 title "Half-wave potential of sulfa drugs as structural index" @default.
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- W2009740282 doi "https://doi.org/10.1016/s0022-0728(80)80094-5" @default.
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