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• W2009753632 abstract "Schiff base derived from naphthylamine and benzil (L) binds to two Cu(2+) ions, one by coordination through N of the Schiff base and another by pi cation interaction through benzil rings. This bonding pattern determined by DFT calculation has been proved by matching electronic spectrum obtained from TDDFT calculation to the experimental one. L acts as on-off fluorescent and bare eye detectable colorimetric (purple color) sensor for Cu(2+) ion over the metal ions - Na(+), K(+), Ca(2+) Mn(2+), Co(2+) Ni(2+), Zn(2+), Pb(2+), Cd(2+), Hg(2+), Ag(+), Hg(2+) and Al(3+) in 1:1 v/v CH3CN:H2O. These metal ions do not interfere the fluorescent/colorimetric sensing. As fluorescent sensor the linear range of detection is 5×10(-5) to 3×10(-4)M and detection limit 10(-5)M." @default.
• W2009753632 created "2016-06-24" @default.
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• W2009753632 date "2015-03-01" @default.
• W2009753632 modified "2023-09-28" @default.
• W2009753632 title "New duel fluorescent “on–off” and colorimetric sensor for Copper(II): Copper(II) binds through N coordination and pi cation interaction to sensor" @default.
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• W2009753632 doi "https://doi.org/10.1016/j.saa.2014.11.030" @default.
• W2009753632 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25479104" @default.
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