FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2009756843> ?p ?o ?g. }

• W2009756843 endingPage "112" @default.
• W2009756843 startingPage "107" @default.
• W2009756843 abstract "The preparation of dialkyl- and diaryltin(IV) N,N′-dialkylmonothiocarbamates from the alkylammonium salt of the ligand and the appropriate diorganotin(IV) chlorides is described. The compounds R2Sn(R′2mtc)2 and Ph3Sn(R′2 mtc) (R = alkyl, aryl; R′2 = Me, Et; mtc = monothiocarbamate anion) are monomeric in dichloromethane or chloroform and are non-electrolytes in nitromethane. 1H spectra of CDCl3 CD2Cl2 and benzene solutions of R2Sn(R′2mtc)2 indicate that the dialkyltin(IV) moiety is non-linear (J119Sn-1HCH3 ca. 80 Hz) and that the N-alkyl substituents in the monothiocarbamate ligand are magnetically non-equivalent. Stereochemical non-rigidity of Me2Sn(Me2mtc)2 in CD2Cl2 is observed in the 1H nmr spectrum. Two isomeric species are observed with coalescence occurring at −30° to give a single species that shows restricted rotation of the N-methyl substituents. Further coalescence of these two equal intensity N-methyl signals occurs at 55 °C. A value of J119Sn--CH3(1J = 552 Hz) for the carbon bonded directly to tin in Et2Sn(Me2mtc)2 suggests that this type of compound involves six-coordination of the tin atom with SnS bonding being stronger than Sn-O bonding. The Ph3Sn(R′2mtc) species have distorted trigonal bipyramidal geometry with the oxygen of the bidentate monothiocarbamate in one of the axial positions." @default.
• W2009756843 created "2016-06-24" @default.
• W2009756843 creator A5047222818 @default.
• W2009756843 creator A5059138388 @default.
• W2009756843 creator A5076473748 @default.
• W2009756843 date "1979-01-01" @default.
• W2009756843 modified "2023-10-18" @default.
• W2009756843 title "Synthesis and characterization of alkyl- and aryltin(IV) monothiocarbamates" @default.
• W2009756843 cites W1964196990 @default.
• W2009756843 cites W1965234531 @default.
• W2009756843 cites W1967937365 @default.
• W2009756843 cites W1982194001 @default.
• W2009756843 cites W1984852798 @default.
• W2009756843 cites W1990177397 @default.
• W2009756843 cites W2001895386 @default.
• W2009756843 cites W2003259467 @default.
• W2009756843 cites W2007484072 @default.
• W2009756843 cites W2010588501 @default.
• W2009756843 cites W2014046850 @default.
• W2009756843 cites W2020874354 @default.
• W2009756843 cites W2028205066 @default.
• W2009756843 cites W2028828641 @default.
• W2009756843 cites W2030385162 @default.
• W2009756843 cites W2034588259 @default.
• W2009756843 cites W2034762761 @default.
• W2009756843 cites W2040663511 @default.
• W2009756843 cites W2043977695 @default.
• W2009756843 cites W2055549592 @default.
• W2009756843 cites W2064553340 @default.
• W2009756843 cites W2069851242 @default.
• W2009756843 cites W2072281573 @default.
• W2009756843 cites W2081009675 @default.
• W2009756843 cites W2084020570 @default.
• W2009756843 cites W2088283294 @default.
• W2009756843 cites W2088725296 @default.
• W2009756843 cites W2157314415 @default.
• W2009756843 cites W2330443213 @default.
• W2009756843 cites W2333830954 @default.
• W2009756843 cites W2334225515 @default.
• W2009756843 cites W2950609812 @default.
• W2009756843 cites W2951236328 @default.
• W2009756843 cites W3004615960 @default.
• W2009756843 cites W3137123003 @default.
• W2009756843 cites W3138946218 @default.
• W2009756843 cites W4254114708 @default.
• W2009756843 doi "https://doi.org/10.1016/s0020-1693(00)94686-3" @default.
• W2009756843 hasPublicationYear "1979" @default.
• W2009756843 type Work @default.
• W2009756843 sameAs 2009756843 @default.
• W2009756843 citedByCount "11" @default.
• W2009756843 countsByYear W20097568432018 @default.
• W2009756843 crossrefType "journal-article" @default.
• W2009756843 hasAuthorship W2009756843A5047222818 @default.
• W2009756843 hasAuthorship W2009756843A5059138388 @default.
• W2009756843 hasAuthorship W2009756843A5076473748 @default.
• W2009756843 hasConcept C111592845 @default.
• W2009756843 hasConcept C115624301 @default.
• W2009756843 hasConcept C116569031 @default.
• W2009756843 hasConcept C155647269 @default.
• W2009756843 hasConcept C170493617 @default.
• W2009756843 hasConcept C178516000 @default.
• W2009756843 hasConcept C178790620 @default.
• W2009756843 hasConcept C179104552 @default.
• W2009756843 hasConcept C185592680 @default.
• W2009756843 hasConcept C2776568683 @default.
• W2009756843 hasConcept C2778870691 @default.
• W2009756843 hasConcept C2780263894 @default.
• W2009756843 hasConcept C2781076698 @default.
• W2009756843 hasConcept C2781144210 @default.
• W2009756843 hasConcept C525849907 @default.
• W2009756843 hasConcept C55493867 @default.
• W2009756843 hasConcept C71240020 @default.
• W2009756843 hasConcept C8010536 @default.
• W2009756843 hasConceptScore W2009756843C111592845 @default.
• W2009756843 hasConceptScore W2009756843C115624301 @default.
• W2009756843 hasConceptScore W2009756843C116569031 @default.
• W2009756843 hasConceptScore W2009756843C155647269 @default.
• W2009756843 hasConceptScore W2009756843C170493617 @default.
• W2009756843 hasConceptScore W2009756843C178516000 @default.
• W2009756843 hasConceptScore W2009756843C178790620 @default.
• W2009756843 hasConceptScore W2009756843C179104552 @default.
• W2009756843 hasConceptScore W2009756843C185592680 @default.
• W2009756843 hasConceptScore W2009756843C2776568683 @default.
• W2009756843 hasConceptScore W2009756843C2778870691 @default.
• W2009756843 hasConceptScore W2009756843C2780263894 @default.
• W2009756843 hasConceptScore W2009756843C2781076698 @default.
• W2009756843 hasConceptScore W2009756843C2781144210 @default.
• W2009756843 hasConceptScore W2009756843C525849907 @default.
• W2009756843 hasConceptScore W2009756843C55493867 @default.
• W2009756843 hasConceptScore W2009756843C71240020 @default.
• W2009756843 hasConceptScore W2009756843C8010536 @default.
• W2009756843 hasLocation W20097568431 @default.
• W2009756843 hasOpenAccess W2009756843 @default.
• W2009756843 hasPrimaryLocation W20097568431 @default.
• W2009756843 hasRelatedWork W1480924375 @default.
• W2009756843 hasRelatedWork W1991957997 @default.
• W2009756843 hasRelatedWork W2074857616 @default.
• W2009756843 hasRelatedWork W2299503928 @default.

• next