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- W2009792803 abstract "Der substituierte Glycolaldehyd 4, der eine enantiomerenreine acetalische Schutzgruppe mit der Konfiguration eines α-L-Zukkers am acetalischen Zentrum tragt, wird unter basischen Bedingungen aldolisiert. Die entstehenden Produkte werden nach Reduktion durch Vergleich mit Referenzverbindungen bekannter Absolutkonfiguration charakterisiert. Es entstehen uberwiegend L-Zucker mit L-Erythrose als Hauptprodukt.Chiral Lactols, VIII. – A Way for the Asymmetric Induction in the Formation of SugarsThe substituted glycol aldehyde 4 which bears an enantiomerically pure acetal-type protective group exhibiting the configuration of an α-L-sugar at the acetal centre is subjected to aldolization under basic conditions. The resulting products are reduced and characterized by comparison with reference compounds of known absolute configuration. L-Sugars are formed preferentially with L-erythrose being the main product." @default.
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- W2009792803 date "1989-07-17" @default.
- W2009792803 modified "2023-09-26" @default.
- W2009792803 title "Chirale Lactole, VIII Ein Weg zur asymmetrischen Induktion bei der Bildung von Zuckern" @default.
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- W2009792803 doi "https://doi.org/10.1002/jlac.198919890206" @default.
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