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- W2009794843 abstract "A calcium ferro-aluminate with composition CaAl 1.8 Fe 0.2 O 4 has been synthesized. The crystal structure of the phase was studied by X-ray single crystal diffraction and refined to an R 1-index value of 0.033, for 1287 observed independent reflections, collected with graphite monochromatized Mo K α-radiation. The compound crystallizes in the monoclinic space group P 12 1 / n l with Z = 12. Cell parameters were a = 8.758(1) A, b = 8.112(1) A, c = 15.311(1) A, β = 90.21(1)°. The crystal structure is characterized by layers of six-membered tetrahedral rings of ditrigonal shape showing two different ring conformations of up (U) and down (D) pointing vertices: UUDUDD and UDUDUD, respectively. The stacking of layers comprises a three-dimensional framework containing channels that are occupied by the calcium cations. The structure is isotypic with CaAl 2 O 4 , the major compound of calcium aluminate cements." @default.
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- W2009794843 date "2001-03-30" @default.
- W2009794843 modified "2023-09-25" @default.
- W2009794843 title "On the Al/Fe substitution in iron doped monocalcium aluminate - the crystal structure of CaAl1.8Fe0.2O4" @default.
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- W2009794843 doi "https://doi.org/10.1127/0935-1221/01/0013-0403" @default.
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