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• W2009804893 abstract "Shock wave studies of the lanthanide series show the existence of a very high pressure phase transition in all members of the series. The data show that this transformation is of necessity to a more incompressible phase and has been identified with melting. Thermodynamic considerations allow calculation of the solid-liquid phase boundary from these data; the results indicate that all the rare earths melt anomalously at sufficiently high pressures. This can be understood in the context of a “two-fluid” theory, in which the composition of the liquid along the phase boundary changes continuously with pressure due to the degree of pressure-induced electronic transition present in the liquid. Hence, at sufficiently high pressure, the density of the liquid becomes greater than the density of the contiguous solid and dPdT becomes negative." @default.
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• W2009804893 date "1975-07-01" @default.
• W2009804893 modified "2023-10-17" @default.
• W2009804893 title "Hugoniot equation of state of the lanthanides" @default.
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• W2009804893 doi "https://doi.org/10.1016/0022-3697(75)90097-9" @default.
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