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• W2009808529 abstract "The high-pressure mesomorphic behavior of a chiral liquid crystalline polyacrylate has been studied by x-ray diffraction in situ. The results show the existence of monolayer smectic-A and bilayer smectic-C mesophases that coexist in the thermally untreated sample over a well-defined range of temperatures, from ambient pressure up to 133 MPa. Hydrostatic pressures of the order of 100--220 MPa are found to affect strongly the polymorphic behavior of the sample. The smectic-A mesophase, which at ambient pressure coexists with an interdigitated smectic-C structure, is stabilized over a temperature range which increases with pressure, whereas the formation of the smectic-C phase is inhibited above 220 MPa. The pressure increment is found to introduce static positional disorder, and to reduce the long-range positional order in the smectic structure strongly. A transition sequence from the isotropic melt through the smectic-A phase to a new crystalline structure is found by cooling isobarically down to room temperature. The proposed pressure-temperature phase diagram suggests the occurrence of peculiar disorder-order-disorder transitions as pressure is reduced isothermally." @default.
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• W2009808529 date "1997-06-01" @default.
• W2009808529 modified "2023-10-14" @default.
• W2009808529 title "High-pressure mesomorphic behavior of a chiral polyacrylate by x-ray diffraction in situ" @default.
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• W2009808529 doi "https://doi.org/10.1103/physreve.55.7121" @default.
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