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• W2009835534 abstract "We have investigated charge transport in ZnTPPdT-Pyr (TPPdT: 5,15-di(p-thiolphenyl)-10,20-di(p-tolyl)porphyrin) molecular junctions using the lithographic mechanically controllable break-junction (MCBJ) technique at room temperature and cryogenic temperature (6 K). We combined low-bias statistical measurements with spectroscopy of the molecular levels in the form of I(V) characteristics. This combination allows us to characterize the transport in a molecular junction in detail. This complex molecule can form different junction configurations, having an observable effect on the trace histograms and the current-voltage (I(V)) measurements. Both methods show that multiple, stable single-molecule junction configurations can be obtained by modulating the interelectrode distance. In addition we demonstrate that different ZnTPPdT-Pyr junction configurations can lead to completely different spectroscopic features with the same conductance values. We show that statistical low-bias conductance measurements should be interpreted with care, and that the combination with I(V) spectroscopy represents an essential tool for a more detailed characterization of the charge transport in a single molecule." @default.
• W2009835534 created "2016-06-24" @default.
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• W2009835534 date "2011-10-18" @default.
• W2009835534 modified "2023-09-23" @default.
• W2009835534 title "Charge transport in a zinc–porphyrin single-molecule junction" @default.
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• W2009835534 doi "https://doi.org/10.3762/bjnano.2.77" @default.
• W2009835534 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/3201625" @default.
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