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• W2009840708 abstract "We discuss the transport of small gas molecules in organic glassy matrices using oxygen diffusion in propylene carbonate as an example. The jumps of a penetrant from one interstitial cavity to another require energy to expand the channel between cavities to the size of the penetrant. It has been established that at temperatures below and slightly above the glass transition temperature, the activation energy of oxygen diffusion, E, is related to the instantaneous shear modulus G∞ of propylene carbonate via the equation E = V × G∞, where V is the temperature-independent parameter that characterizes the volume of the channel. Consequently, the E value is the work necessary for elastic deformation of the surrounding matrix to expand the channel available for oxygen diffusion." @default.
• W2009840708 created "2016-06-24" @default.
• W2009840708 creator A5035460968 @default.
• W2009840708 date "2013-09-20" @default.
• W2009840708 modified "2023-09-27" @default.
• W2009840708 title "Relation between the activation energy of oxygen diffusion and the instantaneous shear modulus in propylene carbonate near the glass transition temperature" @default.
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• W2009840708 doi "https://doi.org/10.1063/1.4821752" @default.
• W2009840708 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24070296" @default.
• W2009840708 hasPublicationYear "2013" @default.
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