Matches in SemOpenAlex for { <https://semopenalex.org/work/W2009849136> ?p ?o ?g. }
- W2009849136 endingPage "31" @default.
- W2009849136 startingPage "21" @default.
- W2009849136 abstract "Abstract The microwave spectrum of tetracyclanone has been analyzed, resulting in a dipole moment of 3.65 ± 0.02 D. This rather large dipole moment is explained as another manifestation of interactions between the Walsh orbitals of cyclopropyl groups and π-orbitals on substituent groups. We have developed an empirical model, based on the ideas of Hoffmann, for the effect of such an interaction on the dipole moment, and show that the model gives good quantitative agreement with the dipole moments of many related compounds. The ground state rotational constants, obtained from an iterative least-squares fit to a rigid rotor, are A = 4361.92 ± 0.07, B = 2469.960 ± 0.003, and C = 2028.872 ± 0.003 MHz. The uncertainties are standard deviations determined solely from the goodness of fit to 10 transition frequencies." @default.
- W2009849136 created "2016-06-24" @default.
- W2009849136 creator A5060672458 @default.
- W2009849136 date "1977-10-01" @default.
- W2009849136 modified "2023-09-23" @default.
- W2009849136 title "Microwave spectrum of tetracyclo[3.2.0.02,7.04,6]heptan-3-one and the effect of cyclopropyl-carbonyl group interactions on the dipole moment" @default.
- W2009849136 cites W1595998152 @default.
- W2009849136 cites W1662984673 @default.
- W2009849136 cites W1966306855 @default.
- W2009849136 cites W1968641366 @default.
- W2009849136 cites W1970779952 @default.
- W2009849136 cites W1971962558 @default.
- W2009849136 cites W1973928943 @default.
- W2009849136 cites W1975410546 @default.
- W2009849136 cites W1976506014 @default.
- W2009849136 cites W1977793951 @default.
- W2009849136 cites W1987657124 @default.
- W2009849136 cites W1991622048 @default.
- W2009849136 cites W1993075121 @default.
- W2009849136 cites W1998101155 @default.
- W2009849136 cites W1998490491 @default.
- W2009849136 cites W1998597028 @default.
- W2009849136 cites W1998940989 @default.
- W2009849136 cites W2000144855 @default.
- W2009849136 cites W2001095149 @default.
- W2009849136 cites W2001389679 @default.
- W2009849136 cites W2002977328 @default.
- W2009849136 cites W2005289087 @default.
- W2009849136 cites W2007692328 @default.
- W2009849136 cites W2011096440 @default.
- W2009849136 cites W2011119048 @default.
- W2009849136 cites W2015625457 @default.
- W2009849136 cites W2020653910 @default.
- W2009849136 cites W2020993928 @default.
- W2009849136 cites W2023614782 @default.
- W2009849136 cites W2023795673 @default.
- W2009849136 cites W2024745964 @default.
- W2009849136 cites W2024784750 @default.
- W2009849136 cites W2024886448 @default.
- W2009849136 cites W2027228460 @default.
- W2009849136 cites W2027755005 @default.
- W2009849136 cites W2032015804 @default.
- W2009849136 cites W2037582972 @default.
- W2009849136 cites W2042024699 @default.
- W2009849136 cites W2044615526 @default.
- W2009849136 cites W2048675459 @default.
- W2009849136 cites W2053959470 @default.
- W2009849136 cites W2054267453 @default.
- W2009849136 cites W2054354313 @default.
- W2009849136 cites W2058512895 @default.
- W2009849136 cites W2062377732 @default.
- W2009849136 cites W2064344915 @default.
- W2009849136 cites W2065135058 @default.
- W2009849136 cites W2072396884 @default.
- W2009849136 cites W2072756469 @default.
- W2009849136 cites W2074523407 @default.
- W2009849136 cites W2075431223 @default.
- W2009849136 cites W2078349734 @default.
- W2009849136 cites W2084472933 @default.
- W2009849136 cites W2086451633 @default.
- W2009849136 cites W2092238279 @default.
- W2009849136 cites W2093184988 @default.
- W2009849136 cites W2163189765 @default.
- W2009849136 cites W2323155281 @default.
- W2009849136 cites W2950267860 @default.
- W2009849136 cites W3005140194 @default.
- W2009849136 cites W3005314052 @default.
- W2009849136 cites W4234899185 @default.
- W2009849136 cites W4236462876 @default.
- W2009849136 cites W4250961913 @default.
- W2009849136 cites W2063329238 @default.
- W2009849136 doi "https://doi.org/10.1016/0022-2852(77)90416-7" @default.
- W2009849136 hasPublicationYear "1977" @default.
- W2009849136 type Work @default.
- W2009849136 sameAs 2009849136 @default.
- W2009849136 citedByCount "5" @default.
- W2009849136 crossrefType "journal-article" @default.
- W2009849136 hasAuthorship W2009849136A5060672458 @default.
- W2009849136 hasConcept C121332964 @default.
- W2009849136 hasConcept C156778621 @default.
- W2009849136 hasConcept C173523689 @default.
- W2009849136 hasConcept C179254644 @default.
- W2009849136 hasConcept C184779094 @default.
- W2009849136 hasConcept C44838205 @default.
- W2009849136 hasConcept C46141821 @default.
- W2009849136 hasConcept C62520636 @default.
- W2009849136 hasConceptScore W2009849136C121332964 @default.
- W2009849136 hasConceptScore W2009849136C156778621 @default.
- W2009849136 hasConceptScore W2009849136C173523689 @default.
- W2009849136 hasConceptScore W2009849136C179254644 @default.
- W2009849136 hasConceptScore W2009849136C184779094 @default.
- W2009849136 hasConceptScore W2009849136C44838205 @default.
- W2009849136 hasConceptScore W2009849136C46141821 @default.
- W2009849136 hasConceptScore W2009849136C62520636 @default.
- W2009849136 hasIssue "1" @default.
- W2009849136 hasLocation W20098491361 @default.
- W2009849136 hasOpenAccess W2009849136 @default.
- W2009849136 hasPrimaryLocation W20098491361 @default.