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- W2009885280 abstract "Three bis(homoleptic) titanium complexes of hydroxyamino-1,3,5-triazine ligands were synthesized and characterized, and their kinetic behavior in THF-water solutions was studied at various pH conditions using UV-vis, based on the characteristic Ti-O band at 380 nm. One of these complexes, , was analyzed by X-ray crystallography. Due to the characteristic electronic structure of the triazine rings, high electron density on the nitrogen atoms leads to strong N-Ti bonds, as indicative by the 2.0 A coordinative bond lengths in the X-ray structure. Consequently, these complexes exhibit high hydrolytic stability over a wide pH range, where hydrolysis was observed to be promoted by basic conditions. At neutral pH, t(1/2) was estimated to be >200 h, whereas at pH = 5.5, no hydrolysis was observed for a period of at least three days." @default.
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- W2009885280 date "2006-01-01" @default.
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- W2009885280 title "Distinctive structural features of hydroxyamino-1,3,5-triazine ligands leading to enhanced hydrolytic stability of their titanium complexes" @default.
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- W2009885280 doi "https://doi.org/10.1039/b606072b" @default.
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