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- W2009899089 abstract "p-Chlorotetrafluorophenyl (Tfc) esters of protected amino acids and peptides are more reactive than are the well known pentafluorophenyl (Pfp) esters. Two reagents, p-chlorotetrafluorophenyltrifluoroacetate (Tfc-OTfa) and di-(p-chlorotetrafluorophenyl)carbonate (di-Tfc-carbonate), can be used for their syntheses, thereby avoiding use of the allergic dicyclohexylcarbodiimide. This is especially important for bulk preparations. Many Fmoc- and Boc-amino acid-OTfc esters have been synthesized and characterized. The hexadecameric tandem repeat H-(AlaAlaLysPro)4-OH was synthesized using di-Tfc-carbonate for the preparation of Tfc-esters." @default.
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- W2009899089 date "2009-01-12" @default.
- W2009899089 modified "2023-09-26" @default.
- W2009899089 title "p-Chlorotetrafluorophenyl esters of N-protected amino acids" @default.
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- W2009899089 doi "https://doi.org/10.1111/j.1399-3011.1994.tb00185.x" @default.
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