FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2009953277> ?p ?o ?g. }

• W2009953277 endingPage "324" @default.
• W2009953277 startingPage "320" @default.
• W2009953277 abstract "The room temperature adsorption of dinitrogen on CuZSM-5 zeolite was studied using diffuse-reflectance infrared spectroscopy (DRIFTS). In addition to an intense absorption band at 2294 cm−1, a weak band at 2207 cm−1 in the region of NN stretching vibrations was also detected in the spectra. Surprisingly, this latter band increases in intensity when the dinitrogen pressure decreases. This band was assigned to internuclear bridging dinitrogen molecules in copper–dinitrogen complexes formed following the adsorption of dinitrogen on CuZSM-5. Quantum-chemical calculations of model zeolite–2Cu(I)–nN2 compounds were performed to confirm the assignment of the bands in the DRIFT spectra of adsorbed N2. It is suggested that at high dinitrogen pressures the formation of a binuclear zeolite–2Cu(I)–3N2 complex containing both terminal on-top and bridging end-on dinitrogen molecules takes place. At low dinitrogen pressures the terminal molecules are removed and the complex is transformed to one containing only an internuclear dinitrogen ligand. The internuclear coordination could explain the high efficiency of CuZSM-5 for dinitrogen adsorption." @default.
• W2009953277 created "2016-06-24" @default.
• W2009953277 creator A5013665296 @default.
• W2009953277 creator A5084940201 @default.
• W2009953277 date "2006-09-01" @default.
• W2009953277 modified "2023-09-25" @default.
• W2009953277 title "DRIFTS evidence for the formation of binuclear Cu(I)–dinitrogen complexes upon adsorption of N2 on CuZSM-5" @default.
• W2009953277 cites W1967199844 @default.
• W2009953277 cites W1975267448 @default.
• W2009953277 cites W1975658141 @default.
• W2009953277 cites W1978133662 @default.
• W2009953277 cites W1982356449 @default.
• W2009953277 cites W1985750401 @default.
• W2009953277 cites W1992822636 @default.
• W2009953277 cites W1994005387 @default.
• W2009953277 cites W1999632943 @default.
• W2009953277 cites W2003111425 @default.
• W2009953277 cites W2008266675 @default.
• W2009953277 cites W2021626264 @default.
• W2009953277 cites W2021725917 @default.
• W2009953277 cites W2030403132 @default.
• W2009953277 cites W2034944207 @default.
• W2009953277 cites W2036140602 @default.
• W2009953277 cites W2038898294 @default.
• W2009953277 cites W2042344544 @default.
• W2009953277 cites W2048025555 @default.
• W2009953277 cites W2065018695 @default.
• W2009953277 cites W2070936403 @default.
• W2009953277 cites W2071323684 @default.
• W2009953277 cites W2086741740 @default.
• W2009953277 cites W2086957099 @default.
• W2009953277 cites W2109019615 @default.
• W2009953277 cites W2123179339 @default.
• W2009953277 cites W2141685773 @default.
• W2009953277 cites W2143981217 @default.
• W2009953277 cites W2168177028 @default.
• W2009953277 doi "https://doi.org/10.1016/j.micromeso.2006.04.005" @default.
• W2009953277 hasPublicationYear "2006" @default.
• W2009953277 type Work @default.
• W2009953277 sameAs 2009953277 @default.
• W2009953277 citedByCount "26" @default.
• W2009953277 countsByYear W20099532772012 @default.
• W2009953277 countsByYear W20099532772014 @default.
• W2009953277 countsByYear W20099532772015 @default.
• W2009953277 countsByYear W20099532772016 @default.
• W2009953277 countsByYear W20099532772018 @default.
• W2009953277 countsByYear W20099532772019 @default.
• W2009953277 countsByYear W20099532772021 @default.
• W2009953277 crossrefType "journal-article" @default.
• W2009953277 hasAuthorship W2009953277A5013665296 @default.
• W2009953277 hasAuthorship W2009953277A5084940201 @default.
• W2009953277 hasConcept C102931765 @default.
• W2009953277 hasConcept C119824511 @default.
• W2009953277 hasConcept C120665830 @default.
• W2009953277 hasConcept C121332964 @default.
• W2009953277 hasConcept C1276947 @default.
• W2009953277 hasConcept C147789679 @default.
• W2009953277 hasConcept C150394285 @default.
• W2009953277 hasConcept C153642686 @default.
• W2009953277 hasConcept C161790260 @default.
• W2009953277 hasConcept C174348530 @default.
• W2009953277 hasConcept C178790620 @default.
• W2009953277 hasConcept C179104552 @default.
• W2009953277 hasConcept C185592680 @default.
• W2009953277 hasConcept C191274033 @default.
• W2009953277 hasConcept C2778077586 @default.
• W2009953277 hasConcept C31258907 @default.
• W2009953277 hasConcept C32909587 @default.
• W2009953277 hasConcept C41008148 @default.
• W2009953277 hasConcept C4839761 @default.
• W2009953277 hasConcept C544778455 @default.
• W2009953277 hasConcept C55352516 @default.
• W2009953277 hasConcept C62520636 @default.
• W2009953277 hasConcept C75473681 @default.
• W2009953277 hasConcept C82261727 @default.
• W2009953277 hasConceptScore W2009953277C102931765 @default.
• W2009953277 hasConceptScore W2009953277C119824511 @default.
• W2009953277 hasConceptScore W2009953277C120665830 @default.
• W2009953277 hasConceptScore W2009953277C121332964 @default.
• W2009953277 hasConceptScore W2009953277C1276947 @default.
• W2009953277 hasConceptScore W2009953277C147789679 @default.
• W2009953277 hasConceptScore W2009953277C150394285 @default.
• W2009953277 hasConceptScore W2009953277C153642686 @default.
• W2009953277 hasConceptScore W2009953277C161790260 @default.
• W2009953277 hasConceptScore W2009953277C174348530 @default.
• W2009953277 hasConceptScore W2009953277C178790620 @default.
• W2009953277 hasConceptScore W2009953277C179104552 @default.
• W2009953277 hasConceptScore W2009953277C185592680 @default.
• W2009953277 hasConceptScore W2009953277C191274033 @default.
• W2009953277 hasConceptScore W2009953277C2778077586 @default.
• W2009953277 hasConceptScore W2009953277C31258907 @default.
• W2009953277 hasConceptScore W2009953277C32909587 @default.
• W2009953277 hasConceptScore W2009953277C41008148 @default.
• W2009953277 hasConceptScore W2009953277C4839761 @default.
• W2009953277 hasConceptScore W2009953277C544778455 @default.
• W2009953277 hasConceptScore W2009953277C55352516 @default.
• W2009953277 hasConceptScore W2009953277C62520636 @default.
• W2009953277 hasConceptScore W2009953277C75473681 @default.

• next