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- W2009960149 abstract "The synthesis of a soluble poly(para-phenylene) (PPP) derivative with two p-carboxyphenoxymethylene substituents in the 2,5-positions of every alternate phenylene moiety is described, transforming a bromomethylene-substituted precursor PPP in a two-step reaction sequence. Both of these steps, namely a Williamson reaction and an ester cleavage using anhydrous potassium hydroxide, occur selectively and almost quantitatively (>98%, n.m.r.). Structurally homogeneous, rigid-rod polyelectrolytes with 80–130 phenylene rings attached to each other may be obtained by this method." @default.
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- W2009960149 date "1993-01-01" @default.
- W2009960149 modified "2023-10-14" @default.
- W2009960149 title "Rigid-rod polyelectrolytes: carboxylated poly(para-phenylene)s via a novel precursor route" @default.
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- W2009960149 doi "https://doi.org/10.1016/0032-3861(93)90136-x" @default.
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