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• W2009974144 abstract "Precise ab initio calculations of the rovibrational structures of the ${A}^{2}{E}^{ensuremath{'}ensuremath{'}}$ and ${X}^{2}{E}^{ensuremath{'}}$ electronic states of ${mathrm{Na}}_{3}$ prompt a new vibrational assignment of the $Aensuremath{leftarrow}X$ transition and provide the basis for the rotational analysis of the vibrational band $A({v}_{s}{phantom{rule{0ex}{0ex}}=phantom{rule{0ex}{0ex}}1,v}_{b}{phantom{rule{0ex}{0ex}}=phantom{rule{0ex}{0ex}}0,v}_{a}phantom{rule{0ex}{0ex}}=phantom{rule{0ex}{0ex}}0)ensuremath{leftarrow}X(0,0,0)$ by means of high-resolution optical-optical double resonance. The calculations, which use the single-surface adiabatic approach, reproduce our experimental data only if, as required by theory, a geometric phase of $ensuremath{pi}$ under pseudorotation around the equilateral configuration is imposed. We consider this the first verification of Berry's phase in high-resolution molecular spectroscopy." @default.
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• W2009974144 date "1998-11-23" @default.
• W2009974144 modified "2023-09-27" @default.
• W2009974144 title "Unambiguous Proof for Berry's Phase in the Sodium Trimer: Analysis of the Transition<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msup><mml:mrow><mml:mi mathvariant=italic>A</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msup></mml:mrow><mml:mrow><mml:msup><mml:mrow><mml:mi mathvariant=italic>E</mml:mi></mml:mrow><mml:mrow><mml:mo>′</mml:mo><mml:mo>′</mml:mo></mml:mrow></mml:msup></mml:mrow><mml:mi /><mml:mo>←</mml:mo><mml:mi /><…" @default.
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• W2009974144 doi "https://doi.org/10.1103/physrevlett.81.4584" @default.
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