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- W2010015174 abstract "Gold is found in three different forms in the Emperor golddeposit: as or submicrometer-size inclusions of gold inarsenian pyrite, as visible native gold and/or electrum, and as tellurides (calaverite,krennerite, sylvanite, and petzite). Similarly, Te occurs as invisible telluriumor submicrometer-size inclusions of tellurium in arsenian pyrite, as visiblenative tellurium, and as tellurides. Scanning electron microscopy (SEM),electron probe microanalysis (EPMA), and secondary ion mass spectroscopy (SIMS)show that pyrite from Emperor is among the most Au- (up to 11,057 ppm Au), Te-(up to 5,796 ppm Te), and As-rich (up to 16.60 wt % As) yet reported from anymineral deposit type. Arsenian pyrite manifests itself as uniformly distributedgrains, as As-rich rims on preexisting grains, or as As-rich cores. Theestimated proportion of Au as invisible gold at Emperor ranges from 47 to 92percent, with the remainder of Au occurring predominantly as gold-bearingtellurides. Native gold constitutes <1 percent of the Au budget. Invisiblegold is incorporated in the structure of arsenian pyrite, probably as aAu-bearing complex where Au is coordinated as ionic gold (Au + ). Theunusually high Au content of Te-bearing arsenian pyrite at Emperor most likelyis due to the presence of lamellae of As- and Au-bearing marcasite or Au-bearingarsenopyrite, or a structurally bound Au-Te-bearing complex that allows forgreater amounts of Au and As to be incorporated in pyrite than is generallyassociated with Te-deficient complexes." @default.
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- W2010015174 date "2003-05-01" @default.
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- W2010015174 title "Invisible Gold and Tellurium in Arsenic-Rich Pyrite from theEmperor Gold Deposit, Fiji: Implications for Gold Distribution and Deposition" @default.
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