Matches in SemOpenAlex for { <https://semopenalex.org/work/W2010015776> ?p ?o ?g. }
Showing items 1 to 83 of
83
with 100 items per page.
- W2010015776 endingPage "113" @default.
- W2010015776 startingPage "107" @default.
- W2010015776 abstract "The chemical nature of Z-3-hexene/Ru(0001) bond at different temperatures was studied by reflection-absorption infrared spectroscopy (RAIRS). At 92 K and for low exposures (0.05 L) the results indicate that Z-3-hexene adsorbs non-dissociatively as a di-σ complex. By annealing to 123 K, it dehydrogenates at the Cα carbons (C3 and C4, bonded to the surface), forming a hexyne di-σ/π complex in a mixture of rotational conformers. Upon thermal activation, this complex decomposes by breaking the Cα–Cβ (i.e., C2–C3 and C4–C5) bonds, yielding adsorbed ethylidyne. At 223 K, only this species and residual di-σ/π complex are present on the surface. A different decomposition path is proposed upon direct adsorption of Z-3-hexene at 223 K, since propylidyne appears to be formed on the surface, which implies breaking the C–C double bond with dehydrogenation. Since the behaviour of Z-3-hexene is identical to that of 3-hexyne, and rather different from 1-hexene, these results suggest that the decomposition of unsaturated hydrocarbons on clean Ru(0001) is determined by the position and not by the nature (double or triple bond) of the functionality." @default.
- W2010015776 created "2016-06-24" @default.
- W2010015776 creator A5035903856 @default.
- W2010015776 creator A5042741228 @default.
- W2010015776 creator A5055841064 @default.
- W2010015776 date "2001-06-01" @default.
- W2010015776 modified "2023-09-27" @default.
- W2010015776 title "The chemical behaviour of 3-hexene on the Ru(0001) surface: a characterisation by RAIRS" @default.
- W2010015776 cites W1976374455 @default.
- W2010015776 cites W1983279120 @default.
- W2010015776 cites W2012924233 @default.
- W2010015776 cites W2023562360 @default.
- W2010015776 cites W2027035099 @default.
- W2010015776 cites W2041868476 @default.
- W2010015776 cites W2042701649 @default.
- W2010015776 cites W2060445592 @default.
- W2010015776 cites W2073056485 @default.
- W2010015776 cites W2086420141 @default.
- W2010015776 cites W2091167240 @default.
- W2010015776 cites W2140764005 @default.
- W2010015776 cites W2171804929 @default.
- W2010015776 cites W3198140284 @default.
- W2010015776 doi "https://doi.org/10.1016/s0039-6028(01)00811-1" @default.
- W2010015776 hasPublicationYear "2001" @default.
- W2010015776 type Work @default.
- W2010015776 sameAs 2010015776 @default.
- W2010015776 citedByCount "6" @default.
- W2010015776 countsByYear W20100157762014 @default.
- W2010015776 countsByYear W20100157762018 @default.
- W2010015776 crossrefType "journal-article" @default.
- W2010015776 hasAuthorship W2010015776A5035903856 @default.
- W2010015776 hasAuthorship W2010015776A5042741228 @default.
- W2010015776 hasAuthorship W2010015776A5055841064 @default.
- W2010015776 hasConcept C119889771 @default.
- W2010015776 hasConcept C147789679 @default.
- W2010015776 hasConcept C150394285 @default.
- W2010015776 hasConcept C153642686 @default.
- W2010015776 hasConcept C160434732 @default.
- W2010015776 hasConcept C161790260 @default.
- W2010015776 hasConcept C178213299 @default.
- W2010015776 hasConcept C178790620 @default.
- W2010015776 hasConcept C185592680 @default.
- W2010015776 hasConcept C2776685382 @default.
- W2010015776 hasConcept C2778597550 @default.
- W2010015776 hasConcept C2780953527 @default.
- W2010015776 hasConcept C68381374 @default.
- W2010015776 hasConcept C75473681 @default.
- W2010015776 hasConcept C8010536 @default.
- W2010015776 hasConceptScore W2010015776C119889771 @default.
- W2010015776 hasConceptScore W2010015776C147789679 @default.
- W2010015776 hasConceptScore W2010015776C150394285 @default.
- W2010015776 hasConceptScore W2010015776C153642686 @default.
- W2010015776 hasConceptScore W2010015776C160434732 @default.
- W2010015776 hasConceptScore W2010015776C161790260 @default.
- W2010015776 hasConceptScore W2010015776C178213299 @default.
- W2010015776 hasConceptScore W2010015776C178790620 @default.
- W2010015776 hasConceptScore W2010015776C185592680 @default.
- W2010015776 hasConceptScore W2010015776C2776685382 @default.
- W2010015776 hasConceptScore W2010015776C2778597550 @default.
- W2010015776 hasConceptScore W2010015776C2780953527 @default.
- W2010015776 hasConceptScore W2010015776C68381374 @default.
- W2010015776 hasConceptScore W2010015776C75473681 @default.
- W2010015776 hasConceptScore W2010015776C8010536 @default.
- W2010015776 hasLocation W20100157761 @default.
- W2010015776 hasOpenAccess W2010015776 @default.
- W2010015776 hasPrimaryLocation W20100157761 @default.
- W2010015776 hasRelatedWork W1978811353 @default.
- W2010015776 hasRelatedWork W2024004742 @default.
- W2010015776 hasRelatedWork W2052572538 @default.
- W2010015776 hasRelatedWork W2053430831 @default.
- W2010015776 hasRelatedWork W2055921389 @default.
- W2010015776 hasRelatedWork W2123134929 @default.
- W2010015776 hasRelatedWork W2345639444 @default.
- W2010015776 hasRelatedWork W2392865202 @default.
- W2010015776 hasRelatedWork W3149667452 @default.
- W2010015776 hasRelatedWork W2674519173 @default.
- W2010015776 hasVolume "482-485" @default.
- W2010015776 isParatext "false" @default.
- W2010015776 isRetracted "false" @default.
- W2010015776 magId "2010015776" @default.
- W2010015776 workType "article" @default.