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- W2010019180 abstract "Ni2P/MCM-41 with a stoichiometric Ni/P ratio prepared using a H2 plasma reduction method was passivated either by 10.0 vol.% H2S/H2 (Ni2P-S) or 1.0 vol.% O2/He (Ni2P-O). The XAS characterization demonstrated that the NiP bond of Ni2P was more sensitive to O2 than the NiNi bond while H2S mainly reacted with NiNi site. Moreover, Ni species in Ni2P-S was more electron-deficient. The different hydrodesulfurization performances of Ni2P-S and Ni2P-O were discussed by considering their different structure and electronic properties as well as the formation of a covalent nickel phosphosulfide phase." @default.
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- W2010019180 date "2014-01-01" @default.
- W2010019180 modified "2023-10-14" @default.
- W2010019180 title "XAS study of Ni2P/MCM-41 passivated by O2/He and H2S/H2" @default.
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- W2010019180 doi "https://doi.org/10.1016/j.catcom.2013.08.026" @default.
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