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- W2010019654 abstract "The ultraviolet (UV) absorption spectra of styrene-alkyl methacrylate and -alkyl acrylate copolymers in chloroform solution altered with changing the styrene content. The molar absorption coefficients at 256. 2 2259. nm were constant over the entire range of composition, while those at 262. 8 and 269. 6 nm decreased with decreasing the styrene content. Hypochromic effects at the latter two wavelengths were observed. Wavelengths of 256. 2 nm and 259. 2 nm can be used as the key bands for the determination of the copolymer composition by UV. The bathochromic shift for the UV spectra of the styrene-alkyl methacrylate copolymers and the hypsochromic shift for those of the styrene-alkyl acrylate copolymers were observed. The hypochromic effect was independent of the types of comonomers; the ester group of the comonomer did not have any influence on UV absorption for the phenyl group. However, a methyl group attached to an a-carbon atom of the methacrylate monomer shifted the peak maxima toward lower absorption energies and a hydrogen atom on an α-carbon atom of the acrylate monomer toward higher absorption energies." @default.
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- W2010019654 date "1990-02-01" @default.
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- W2010019654 title "Influence of Composition on Ultraviolet Absorption Spectra of Styrene-Alkyl Methacrylate and Styrene-Alkyl Acrylate Random Copolymers" @default.
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- W2010019654 doi "https://doi.org/10.2116/analsci.6.27" @default.
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