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- W2010035306 abstract "1 H N.m.r. measurements and differential thermal analyses have been performed on solid propylammonium chloride and bromide, including their N-deuterated analogues. X-Ray powder diffraction and electrical conductivity were measured for the highest-temperature solid phase of NH3(n-C3H7)Cl. The corresponding highest-temperature solid phase of the bromide was determined. These salts have three solid phases below the respective melting temperature. In the highest-temperature phase, having a structure consisting of cation and anion layers, it was found for the chloride that the cations perform self-diffusion in two-dimensional layers. A non-linear log T1vs. T–1 curve observed in the room-temperature phase of propylammonium chloride and bromide could be well explained by assuming a non-Arrhenius type thermal process for the random reorientation of the cation along the cationic chain axis. The broad T1 minimum of NH3(n-C3H7)Br observed in its low-temperature phase has been assigned to two closely spaced T1 minima due to the C3 reorientation of the CH3 and NH+3 groups. Motional parameters for the above cationic motions in the three phases of the present salts have been evaluated, and the features of these motions are discussed." @default.
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- W2010035306 date "1987-01-01" @default.
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- W2010035306 title "Hydrogen-1 nuclear magnetic resonance, differential thermal analysis, X-ray powder diffraction and electrical conductivity studies on the motion of cations, including self-diffusion in crystals of propylammonium chloride and bromide as well as their n-deuterated analogues" @default.
- W2010035306 doi "https://doi.org/10.1039/f19878303207" @default.
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