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- W2010046390 abstract "The reaction between CH3OH or C2H5OH and 1,1-dimethylsilaethene, the disproportionation product of the trimethylsilyl radical, has been studied to establish its efficiency for quantitative measurement of the disproportionation reaction. It has been found that standing in a Pyrex vessel, in mixtures of (CH3)3SiH - the usual precursor of the (CH3)3Si radical - and CH3OH or C2H5OH, a dark surface reaction takes place giving H2, (CH3)3SiSi(CH3)3 and (CH3)3SiOR. Using the Hg(3P1) photosensitization of (CH3)3 SiH as a source of (CH3)3Si radicals in the presence of 10–20 Torr CH3OH or 10 Torr C2H5OH, the (CH3)3SiOR product yield increased linearly with increasing photolysis time but did not vanish when extrapolated to zero time. After minimizing this interfering dark reaction and applying a correction for its contribution we determined the value kd/kc = 0.10±0.01 for the disproportionation-combination reactions of the trimethylsilyl radical." @default.
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- W2010046390 date "1987-12-01" @default.
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- W2010046390 title "Hg(3P1) Photosensitization of trimethylsilane in the presence of alcohol" @default.
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- W2010046390 doi "https://doi.org/10.1016/0009-2614(87)87262-7" @default.
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