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- W2010056469 abstract "The pivotal biosynthetic intermediate directly leading to protoanemonin was established to be 2-oxoglutarate on the basis of the labeling patterns in protoanemonin biosynthesized from sodium acetate-1-14C, sodium malonate-2-14C, sodium succinate-2,3-14C2, sodium glutamate-5-14C, and sodium 2-oxoglutarate-5-14C by Ranunculus glaber. Also the 3H/14C ratio in protoanemonin biosynthesized from (3R)-2-oxoglutaric-3-3H1-3,4-14C2 and 2-oxoglutaric-3-3H2-3,4-14C2 acids demonstrated that the formation of the double bond at the 3-position of protoanemonin involves the stereospecific elimination of the pro-3S hydrogen atom from 2-oxoglutaric acid." @default.
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- W2010056469 date "1982-05-01" @default.
- W2010056469 modified "2023-09-25" @default.
- W2010056469 title "The Biosynthesis of Protoanemonin in<i>Ranunculus glaber</i>. The Pivotal Biosynthetic Intermediate and the Stereospecific Hydrogen Elimination from the Intermediate" @default.
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