Matches in SemOpenAlex for { <https://semopenalex.org/work/W2010072635> ?p ?o ?g. }
Showing items 1 to 66 of
66
with 100 items per page.
- W2010072635 endingPage "1708" @default.
- W2010072635 startingPage "1705" @default.
- W2010072635 abstract "Kinetic isotope effects have been measured for the intramolecular nucleophilic carboxylate-catalyzed hydrolysis, k/sub s/, of mono-p-bromophenyl succinate and mono-p-bromophenyl succinate-d/sub 4/. The resulting isotope effect, k/sub s//sup h/sub 4///k/sub s//sup d/sub 4//, equals 1.035, a normal effect. This is contrary to what is expected for acyl transfer reactions where the transition-state structure resembles a tetrahedral intermediate. However, the direction of the isotope effect is in agreement with a transition-state structure resembling succinic anhydride. Combining this result with previous kinetic and structural studies, a detailed transition-state structure for the hydrolysis reaction is proposed. 31 references, 2 tables." @default.
- W2010072635 created "2016-06-24" @default.
- W2010072635 creator A5003353490 @default.
- W2010072635 creator A5054834913 @default.
- W2010072635 creator A5066095800 @default.
- W2010072635 creator A5076030498 @default.
- W2010072635 creator A5078011460 @default.
- W2010072635 date "1978-04-01" @default.
- W2010072635 modified "2023-09-26" @default.
- W2010072635 title "Secondary isotope effects in intramolecular catalysis. Mono(p-bromophenyl) succinate hydrolysis" @default.
- W2010072635 doi "https://doi.org/10.1021/jo00403a017" @default.
- W2010072635 hasPublicationYear "1978" @default.
- W2010072635 type Work @default.
- W2010072635 sameAs 2010072635 @default.
- W2010072635 citedByCount "11" @default.
- W2010072635 crossrefType "journal-article" @default.
- W2010072635 hasAuthorship W2010072635A5003353490 @default.
- W2010072635 hasAuthorship W2010072635A5054834913 @default.
- W2010072635 hasAuthorship W2010072635A5066095800 @default.
- W2010072635 hasAuthorship W2010072635A5076030498 @default.
- W2010072635 hasAuthorship W2010072635A5078011460 @default.
- W2010072635 hasConcept C121332964 @default.
- W2010072635 hasConcept C155647269 @default.
- W2010072635 hasConcept C161790260 @default.
- W2010072635 hasConcept C172456720 @default.
- W2010072635 hasConcept C178790620 @default.
- W2010072635 hasConcept C185592680 @default.
- W2010072635 hasConcept C58364064 @default.
- W2010072635 hasConcept C62520636 @default.
- W2010072635 hasConcept C69928629 @default.
- W2010072635 hasConcept C71240020 @default.
- W2010072635 hasConcept C75079739 @default.
- W2010072635 hasConcept C94412978 @default.
- W2010072635 hasConceptScore W2010072635C121332964 @default.
- W2010072635 hasConceptScore W2010072635C155647269 @default.
- W2010072635 hasConceptScore W2010072635C161790260 @default.
- W2010072635 hasConceptScore W2010072635C172456720 @default.
- W2010072635 hasConceptScore W2010072635C178790620 @default.
- W2010072635 hasConceptScore W2010072635C185592680 @default.
- W2010072635 hasConceptScore W2010072635C58364064 @default.
- W2010072635 hasConceptScore W2010072635C62520636 @default.
- W2010072635 hasConceptScore W2010072635C69928629 @default.
- W2010072635 hasConceptScore W2010072635C71240020 @default.
- W2010072635 hasConceptScore W2010072635C75079739 @default.
- W2010072635 hasConceptScore W2010072635C94412978 @default.
- W2010072635 hasIssue "9" @default.
- W2010072635 hasLocation W20100726351 @default.
- W2010072635 hasOpenAccess W2010072635 @default.
- W2010072635 hasPrimaryLocation W20100726351 @default.
- W2010072635 hasRelatedWork W1554376873 @default.
- W2010072635 hasRelatedWork W1970786813 @default.
- W2010072635 hasRelatedWork W2000238513 @default.
- W2010072635 hasRelatedWork W2010072635 @default.
- W2010072635 hasRelatedWork W2024004531 @default.
- W2010072635 hasRelatedWork W2036225272 @default.
- W2010072635 hasRelatedWork W2063678345 @default.
- W2010072635 hasRelatedWork W2081699998 @default.
- W2010072635 hasRelatedWork W2975184688 @default.
- W2010072635 hasRelatedWork W4250602175 @default.
- W2010072635 hasVolume "43" @default.
- W2010072635 isParatext "false" @default.
- W2010072635 isRetracted "false" @default.
- W2010072635 magId "2010072635" @default.
- W2010072635 workType "article" @default.