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- W2010074429 abstract "The empirical correlation of the photoelectron spectra of 1,4-cyclohexadiene (molecule 4), 1, 4, 5, 8-tetrahydronaphthalene (molecule 5), 1, 4, 5, 6, 9, 1 0-hexahydroanthracene (molecule 6), and 1, 4, 5, 6, 7, 10, 11, 12-octahydronaphthacene (molecules 6) proves that the electronic ground state of these molecules is 2B1u, assuming that they have D2h symmetry. In particular this confirms previous predictions for 1,4-cyclohexadiene (molecule 4), for which the “inverted” orbital sequence 2b1u(π) above lb3g(π) had been proposed under the assumption that hyperconjugative “through-bond” interaction dominates the “through-space” interaction of the two semi-localized π-orbitals." @default.
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- W2010074429 date "1976-01-01" @default.
- W2010074429 modified "2023-09-27" @default.
- W2010074429 title "Photoelectron spectroscopic assignment of symmetry to the ground state and first excited state of the 1,4-cyclohexadiene radical cation" @default.
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- W2010074429 doi "https://doi.org/10.1016/0368-2048(76)81033-x" @default.
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