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- W2010079215 abstract "Experimental measurements of intrinsic viscosity and radii of gyration of monodisperse samples of polystyrene of molecular weights 2.33 X 105, 4.11 X 105, 6.70 X 105, and 2.3 X 106 dissolved in the homologous series of 1-chloroparaffins from butane to undecane are reported. The dependence of the viscosity expansion coefficient αη on the expansion factor αs for the radius of gyration is discussed in the light of the results obtained by an expansion of the Fixman theory for perturbed chains to include partial draining. These results give support to the finite chain effect on the hydrodynamics of expanded coils in the usual range of molecular weight. The exponent a in the relation α3η = αas depends on molecular weight and agrees with recent nondraining theoretical calculation for exceedingly high polymers." @default.
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- W2010079215 date "1979-02-01" @default.
- W2010079215 modified "2023-09-26" @default.
- W2010079215 title "Hydrodynamic interaction effects on intrinsic viscosity of perturbed chains: Experimental results for polystyrene" @default.
- W2010079215 doi "https://doi.org/10.1002/pol.1979.180170203" @default.
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