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• W2010079790 abstract "Abstract Copolymerization of butadiene (Bd) with styrene (St) was carried out by a catalytic system composed of Nd(versatate)3 (Nd(vers)3), Al(i‐Bu)3, and chloroform. The catalyst system exhibited a high catalytic activity and high stereospecificity of Bd in the copolymerization. The effects of Al/Nd molar ratio, Cl/Nd molar ratio, polymerization time, and monomer feed ratio on the copolymerization were thoroughly studied. It is found that the cis‐selectivity for Bd units of this catalyst was disturbed slightly by incorporating St unit in the copolymers, quite different from some other rare earth catalysts, and this is supposed to be related with monomer reactivity ratio of St (r St) in the copolymerization system." @default.
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• W2010079790 date "2004-12-29" @default.
• W2010079790 modified "2023-10-16" @default.
• W2010079790 title "Copolymerization of Butadiene with Styrene by Nd(vers)₃–Al(i‐Bu)₃–CHCl₃Catalyst System" @default.
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• W2010079790 doi "https://doi.org/10.1081/ma-120027175" @default.
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