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- W2010091657 abstract "The reaction of 1,1-dimethyl-trans-2,3,-bis(2′,2′-dimethylcyclopropylidene)-1-silirane with S8 gives a mixture of four isomeric products derived from incorporation of one sulfur atom and a cyclopropylcarbinyl-to-butenyl type rearrangement. This silirane reacts with t-butyl mercaptan to give a product of mercaptan addition in which a cyclopropylcarbinyl-to-butenyl rearrangement also has occurred. Hexamethylsilirane reacts with S8 to give 1,1,4,4,5,5-hexamethyl-2,3-dithia-1-silacyclopentane in high yield. These reactions are discussed in terms of free radical mechanisms." @default.
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- W2010091657 date "1979-01-01" @default.
- W2010091657 modified "2023-10-16" @default.
- W2010091657 title "Reactions of siliranes with elemental sulfur and with t-butyl mercaptan. Preparation of the 2,3-dithia-1-silacyclopentane ring system" @default.
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- W2010091657 doi "https://doi.org/10.1016/s0022-328x(00)81694-0" @default.
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