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- W2010102318 abstract "A kinetic method for the determination of submicrogram amounts of iodide is described. The method is based on the catalytic effect of iodide on the ligand substitution reaction of the mercury(II)-4-(2-pyridylazo)resorcinol complex with 1,2-cyclohexanediamine-N,N,N',N'-tetraacetic acid. Iodide concentrations as low as 10−8M can be determined. Chloride and bromide do not interfere at least up to 5·10−4M and 10−5M, respectively. Cationic interferences can be removed by preliminary ion exchange. On décrit une méthode pour le dosage des iodures (en quantité de l'ordre du submicrogramme). Elle est basée sur l'action catalytique des iodures dans la réaction de substitution du complexe mercure(II)-4-(2-pyridylazo)résorcinol avec l'acide l,2-cyclohexanediamino-N,N,N',N'-tétracétique. Chlorure (5·10−4M et bromure (10−5M) ne gênent pas. Les interférences cationiques peuvent être éliminées par traitement préliminaire sur échangeur d'ions. Es wird eine kinetische Methode für die Bestimmung von Submikrogramm-Mengen Jodid beschrieben. Die Methode beruht auf der katalytischen Wirkung von Jodid auf die Ligandensubstitutionsreaktion des Quecksilber(II)-4-(2-Pyridylazo)-resorcin-Komplexes mit 1,2-Cyclohexandiamin-N,N,N',N'-tetraessigsäure. Es können Jodidkonzentrationen bis zu 10−8M herab bestimmt werden. Chlorid und Bromid unterhalb 5·10−4M bzw. 10-5M stören nicht. Kationische Störungen können durch vorhergehenden Ionenaustausch entfernt werden." @default.
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- W2010102318 date "1971-12-01" @default.
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- W2010102318 title "Determination of submicrogram amounts of iodide by its catalytic effect on the substitution reaction of mercury(II)-par complex with cydta" @default.
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- W2010102318 doi "https://doi.org/10.1016/s0003-2670(01)95118-9" @default.
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