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- W2010106163 abstract "We report the application of rotor-assisted population transfer (RAPT) to measure the quadrupolar coupling constant (C(q)) for spin 5/2 nuclei. Results from numerical simulations are presented on the magnitude of enhancement factor as a function of frequency offsets, i.e. the RAPT profile. Experimental O17 RAPT profile is traced for the amino acid L-leucine. In addition, results from MQ-MAS experiments are incorporated to determine the quadrupolar asymmetry parameter (eta(q)). Unlike previous reports, the O17 NMR parameters for an amino acid, L-leucine, is reported at a relatively low field of 9.4 T." @default.
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- W2010106163 date "2006-02-01" @default.
- W2010106163 modified "2023-10-16" @default.
- W2010106163 title "A combined RAPT and MQ-MAS NMR study of l-leucine" @default.
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- W2010106163 doi "https://doi.org/10.1016/j.ssnmr.2005.10.007" @default.
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