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- W2010123012 abstract "[Ni(ema)(μ-S,S′)Ni(dppp)] (1) and [Ni(ema)(μ-S,S′)Ni(dppe)] (2) have been prepared as synthetic structural analogues of the Ni–Ni subsite of the A-cluster of the enzyme acetyl-CoA synthase by reaction of [Ni(ema)]2−, H4ema is N,N′-ethylenebis(2-mercaptoacetamide), with [NiCl2(diphos)], diphos is 1,2-bis(diphenylphosphino)propane (dppp) or 1,2-bis(diphenylphosphino)ethane (dppe). A similar reaction with 1,2-bis(diethylphosphino)ethane did not give the dinuclear product but the trinuclear complex [NEt4]2[Ni{Ni(ema)(μ-S,S′)}2] (3). Complexes 1 and 3 have been crystallographically characterised." @default.
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- W2010123012 date "2005-02-01" @default.
- W2010123012 modified "2023-10-17" @default.
- W2010123012 title "Homonuclear dinickel complexes: structural mimics for the dinickel subsite of the A-cluster of acetyl-CoA synthase" @default.
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- W2010123012 doi "https://doi.org/10.1016/j.inoche.2004.11.026" @default.
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