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• W2010132452 endingPage "109" @default.
• W2010132452 startingPage "103" @default.
• W2010132452 abstract "Desolvation in three (solv)M(CO)5 complexes (M=Cr, Mo, W; solv=solvent) produced after pulsed laser flash photolysis in solv/1-hexene mixtures takes place exclusively via dissociative mechanisms. The enthalpies of activation for solvent dissociation, which should closely approximate the solv-M bond strengths, have been determined for the η2-benzene-Mo and η2-benzene-W bonds, in which benzene likely is coordinated to the metal edge-on in a dihapto fashion, and tetrachloromethane-Cr bonds, which involve Cl-to-Cr coordination. These inferred bond strengths are compared to other reported metal-ligand (L) bond strengths derived from kinetics data in solution for LM(CO)5 complexes, and M-alkane bond strengths obtained from time-resolved photoacoustic calorimetric studies." @default.
• W2010132452 created "2016-06-24" @default.
• W2010132452 creator A5001730991 @default.
• W2010132452 creator A5045842234 @default.
• W2010132452 date "1991-03-01" @default.
• W2010132452 modified "2023-10-17" @default.
• W2010132452 title "Octahedral metal carbonyls. 74. Estimates of solvent-metal bond strengths in (solvent)M(CO)5 complexes (solvent=benzene (M=Mo, W) and tetrachloromethane (M=Cr))" @default.
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• W2010132452 doi "https://doi.org/10.1016/s0020-1693(00)85267-6" @default.
• W2010132452 hasPublicationYear "1991" @default.
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